The available columns for any given table are fetched from a system table called "sys_tablecolumns". A specific table name is provided in the WHERE criteria to restrict the table from which the column information is fetched:

import cdata.excelservices as mod
conn = mod.connect("Url=https://myorg.sharepoint.com;[email protected];Password=password;File=Book1.xlsx;")
cur = conn.cursor()
cmd = "SELECT * FROM sys_tablecolumns WHERE TableName = 'Account'"
cur.execute(cmd)
rs = cur.fetchall()
for row in rs:
	print(row)